Bis(2,2′-bipyridyl-κ2 N,N′)(sulfato-κ2 O,O′)cobalt(II) ethane-1,2-diol monosolvate
نویسندگان
چکیده
The title compound, [Co(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), has the Co(2+) ion in a distorted octa-hedral CoN(4)O(2) coordination geometry. A twofold rotation axis passes through the Co and S atoms, and through the mid-point of the C-C bond of the ethane-diol mol-ecule. In the crystal, the [CoSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are held together by a pair of O-H⋯O hydrogen bonds.
منابع مشابه
Bis(2,2′-bipyridyl-κ2 N,N′)(sulfato-κ2 O,O′)zinc(II) ethane-1,2-diol solvate
The title compound, [Zn(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), is a six-coordinate zinc(II) complex with a distorted octa-hedral coordination geometry. The Zn(II) atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2'-bipyridine ligands. The Zn-N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn-O bond distance is 2.18...
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متن کاملPoly[aqua(μ2-4,4′-bipyridine-κ2 N:N′)(ethane-1,2-diol-κO)(μ2-sulfato-κ2 O:O′)nickel(II)]
The title compound, [Ni(SO4)(C10H8N2)(C2H6O2)(H2O)] n , contains two crystallographically unique Ni(II) atoms, each lying on a twofold rotation axis and having a slightly distorted octa-hedral environment. It is isotypic with the previously reported Cu(II) analog [Zhong et al. (2011 ▶). Acta Cryst. C67, m62-m64]. One Ni(II) atom is coordinated by two N atoms from two bridging 4,4'-bipyridine (4...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2010